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The aim of this letter is to check the ultra-relativistic limit of a recent model proposed by Pennisi and Ruggeri [Ann. Phys. 377, 414 (2017)] for a relativistic gas with internal structure. Considering an Eulerian fluid we prove that there exists a critical value of the degree of freedom such that for smaller values of this quantity the ultra relativistic limit of the energy of a gas with structure is the same as the Synge energy for monatomic gases, while for larger degrees of freedom the energy increases with the degree of freedom itself. The limiting equations are accompanied with the explicit expression of the characteristic velocities of the hyperbolic system.

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