We carried out the comparative study of the signal from the decay of double -shell vacancy production that follows after single -shell electron capture of Kr and double -shell electron capture of Kr. The radiative decay of a the double vacancy state was identified by detecting the triple coincidence of two X-rays and several Auger electrons in the -decay, or by detecting two X-rays and (Auger electrons + ejected -shell electron) in the decay. The number of -shell vacancies per the -electron capture, produced as a result of the shake-off process, has been measured for the decay of Kr. The probability for this decay was found to be with a systematic error of . For the decay, the comparative study of single- and double-capture decays allowed us to obtain the signal-to-background ratio to be 15/1. The half-life $T_{1/2}^{2\nu2K}(g.s. \rightarrow g.s.) = [1.9^{+1.3}_{-0.7}(stat)\pm0.3(syst)]\times 10^{22}$ y is determined from the analysis of data that have been accumulated over 782 days of live measurements in the experiment that used samples consisted of 170.6 g of Kr.

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