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Motivated by the recent LHCb observation of doubly-charmed baryon in the final state, we analyze the weak decays of doubly heavy baryons , , , , and under the flavor SU(3) symmetry. Decay amplitudes for various semileptonic and nonleptonic decays are parametrized in terms of a few SU(3) irreducible amplitudes. We find a number of relations or sum rules between decay widths and CP asymmetries, which can be examined in future measurements at experimental facilities like LHC, Belle II and CEPC. Moreover once a few decay branching fractions are measured in future, some of these relations may provide hints for exploration of new decay modes.

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