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Given a klt singularity , we show that a quasi-monomial valuation with a finitely generated associated graded ring is the minimizer of the normalized volume function , if and only if induces a degeneration to a K-semistable log Fano cone singularity. Moreover, such a minimizer is unique among all quasi-monomial valuations up to rescaling. As a consequence, we prove that for a klt singularity on the Gromov-Hausdorff limit of K"ahler-Einstein Fano manifolds, the intermediate K-semistable cone associated to its metric tangent cone is uniquely determined by the algebraic structure of , hence confirming a conjecture by Donaldson-Sun.

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