This paper aims at looking for Frobenius subcategories, via the separated monomorphism category , and on the other hand, to establish an {\rm RSS} equivalence from to its dual . For a bound quiver and an algebra , where is acyclic and is generated by monomial relations, let . For any additive subcategory of -mod, we construct combinatorially. This construction describe Gorenstein-projective -modules as $\mathcal {GP}(\m) = {\rm smon}(Q, I, \mathcal {GP}(A))$. It admits a homological interpretation, and enjoys a reciprocity for a cotilting -module . As an application, has Auslander-Reiten sequences if is resolving and contravariantly finite with -mod. In particular, has Auslander-Reiten sequences. It also admits a filtration interpretation as ${\rm smon}(Q, I, \mathscr{X})={\rm Fil}(\mathscr{X}\otimes \mathcal P(kQ/I))\x{\rm smon}(Q, I, \x)$ is an extension-closed Frobenius subcategory if and only if so is . This gives “new” Frobenius subcategories of -mod in the sense that they are not . Ringel-Schmidmeier-Simson equivalence ${\rm smon}(Q, I, \x)\cong{\rm sepi}(Q, I, \x)$ is introduced and the existence is proved for arbitrary extension-closed subcategories . In particular, the Nakayama functor gives an {\rm RSS} equivalence ${\rm smon}(Q, I, A)\cong{\rm sepi}(Q, I, A)AQI$, an explicit formula of an {\rm RSS} equivalence is found for arbitrary additive subcategories .

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