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We report on the measurement of the scattering properties of ultracold Yb bosons in a three-dimensional (3D) optical lattice. Site occupancy in an atomic Mott insulator is resolved with high-precision spectroscopy on an ultranarrow optical clock transition. Scattering lengths and loss rate coefficients for Yb atoms in different collisional channels involving the ground state S and the metastable P are derived. These studies set important constraints for future experimental studies of two-electron atoms for quantum-technological applications.

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