Absolute frequency determination of molecular transition in the Doppler regime at kHz level of accuracy

We present absolute frequency measurement of the unperturbed P7 P7 O${}_2$ B-band transition with relative standard uncertainty of $2\times {10}^{-11}$. We reached the level of accuracy typical for Doppler-free techniques, with Doppler-limited spectroscopy. The Doppler-limited shapes of the P7 P7 spectral line were measured with a frequency-stabilized cavity ring-down spectrometer referenced to an ${}^{88}$Sr optical atomic clock by an optical frequency comb.