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Vector-boson scattering (VBS) processes provide particularly promising means for probing the mechanism of electroweak symmetry breaking and to search for new physics in the weak sector. In the environment of a future proton-proton collider operating at a center-of-mass energy of 100 TeV, unprecedented opportunities arise for the investigation of this important class of reactions. We highlight the prominent features of VBS processes in this energy regime and discuss how the VBS signal can be isolated in the presence of a priori large QCD backgrounds. We find excellent opportunities for the analysis of VBS reactions in a kinematic range that is inaccessible to present colliders.

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