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We study generalized complex structures and -duality (in the sense of Bouwknegt, Evslin, Hannabuss and Mathai) on Lie algebras and construct the corresponding Cavalcanti and Gualtieri map. Such a construction is called “Infinitesimal -duality”. As an application we deal with the problem of finding symplectic structures on 2-step nilpotent Lie algebras. We also give a criteria for the intregability of the infinitesimal -duality of Lie algebras to topological -duality of the associated nilmanifolds.

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