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In this paper, we investigate the localization of a five-dimensional vector field on a pure geometrical thick brane. In previous work, it was shown that a free massless vector field cannot be localized on such thick brane. Hence we introduce the interaction between the vector field and the background scalar field. Two types of couplings are constructed as examples. We get a typical volcano potential for the first type of coupling and a finite square-well-like potential for the second one. Both of the two types of couplings ensure that the vector zero mode can be localized on the pure geometrical thick brane under some conditions.

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