Interface state densities, , in metal-oxide-semiconductor (MOS) capacitors are rarely reported in the accumulation energy range. It is recognized that the determination of in accumulation is fundamentally obscured by small inaccuracies in the user-defined oxide capacitance, . This source of error prevents the High-Low frequency technique from reporting accumulation , even for sufficiently fast high-frequency measurements. To resolve this, an electrostatic constraint that is uniquely satisfied by a physically consistent is derived from the established theory, thereby completing the High-Low framework. The “completed” framework’s theoretical validity is confirmed using simulated capacitance data for an n-SiC MOS structure, and the method’s frequency limitations are demonstrated. This analytical advancement ensures a physically consistent extraction of near the band edge, overcoming a fundamental limitation in MOS capacitor characterization.

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