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In this paper we prove the optimal upper bound for one-dimensional Schrodinger operators with a nonnegative differentiable and single-barrier potential , such that where . In particular, if satisfies the additional condition , then \frac{\lambda_{n}}{\lambda_{m}}\leq \frac{n^{2}% }{m^{2}} for For this result, we develop a new approach to study the monotonicity of the modified Pr"{u}fer angle function.

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