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A graph is said to be symmetric if its automorphism group is transitive on its arcs. Guo et al. (Electronic J. Combin. 18, #P233, 2011) and Pan et al. (Electronic J. Combin. 20, #P36, 2013) determined all pentavalent symmetric graphs of order . In this paper, we shall generalize this result by determining all connected pentavalent symmetric graphs of order four times an odd square-free integer. It is shown in this paper that, for each of such graphs , either the full automorphism group is isomorphic to , , ${\sf PSL}(2,p){\times}_2{\sf PGL}(2,p){\times}_2\it\Gamma$ is isomorphic to one of 8 graphs.

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