This work reports on accurate, high-resolution measurements of the Mg()Mg and Mg() cross sections in the neutron energy range from thermal to about 300 keV, leading to a significantly improved Mg()Mg parametrization. The relevant resonances for Mg were characterized from a combined R-matrix analysis of the experimental data. This resulted in an unambiguous spin/parity assignment of the corresponding excited states in Mg. With this information experimental upper limits of the reaction rates for Ne()Mg and Ne()Mg were established, potentially leading to a significantly higher ($\alpha, n\alpha, \gamma$) ratio than previously evaluated. The impact of these results have been studied for stellar models in the mass range 2 to 25 .

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