The XMM Cluster Archive Super Survey (X-CLASS) is a serendipitously-detected X-ray-selected sample of 845 galaxy clusters based on 2774 XMM archival observations and covering approximately 90 deg spread across the high-Galactic latitude ( deg) sky. The primary goal of this survey is to produce a well-selected sample of galaxy clusters on which cosmological analyses can be performed. This article presents the photometric redshift followup of a high signal-to-noise subset of 266 of these clusters with declination deg with GROND, a seven channel () simultaneous imager on the MPG 2.2m telescope at the ESO La Silla Observatory. We use a newly developed technique based on the red sequence colour-redshift relation, enhanced with information coming from the X-ray detection to provide photometric redshifts for this sample. We determine photometric redshifts for 236 clusters, finding a median redshift of with an accuracy of $\Delta z = 0.02 (1+z)$ when compared to a sample of 76 spectroscopically confirmed clusters. We also compute X-ray luminosities for the entire sample and find a median bolometric luminosity of and a median temperature 2.9 keV. We compare our results to the XMM-XCS and XMM-XXL surveys, finding good agreement in both samples. The X-CLASS catalogue is available online at http://xmm-lss.in2p3.fr:8080/l4sdb/.

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