Let , and be the Euclidean space equipped with the -dimensional Lebesgue measure. In this article, the authors establish the Fefferman-Stein decomposition of Triebel-Lizorkin spaces on basis of the dual on function set which has special topological structure. The function in Triebel-Lizorkin spaces can be written as the certain combination of functions in . To get such decomposition, {\bf (i),} The authors introduce some auxiliary function space and defined via wavelet expansions. The authors proved $\dot{F}^{0}{1,q} \subsetneqq L^{1} \bigcup \dot{F}^{0}{1,q}\subset {\rm WE}^{1,,q}\subset L^{1} + \dot{F}^{0}{1,q}^{\infty,,q’}(^D)\dot{F}^0{\infty,,q’}(^D)$. {\bf (ii),} The authors establish the Riesz transform characterization of Triebel-Lizorkin spaces by function set $^{1,,q}(\mathbb R^D)^{1,,q}(\mathbb R^D)$. As a consequence of the above results, the authors get also Riesz transform characterization of Triebel-Lizorkin spaces by Banach space . Although Fefferman-Stein type decomposition when was obtained by C.-C. Lin et al. [Michigan Math. J. 62 (2013), 691-703], as was pointed out by C.-C. Lin et al., the approach used in the case can not be applied to the cases , which needs some new methodology.

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