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In this note we further explore the properties of universal enveloping algebras associated to a post-Lie algebra. Emphasizing the role of the Magnus expansion, we analyze the properties of group like-elements belonging to (suitable completions) of those Hopf algebras. Of particular interest is the case of post-Lie algebras defined in terms of solutions of modified classical Yang-Baxter equations. In this setting we will study factorization properties of the aforementioned group-like elements.

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