We study the effect of discrete symmetries on coherent multiple scattering in the quantum kicked rotor. When the initial momentum is set to zero – as in recent Bose-Einstein condensate experiments – the effective pseudo-disorder becomes even under momentum inversion. The resulting discrete mirror symmetry of the dynamics profoundly alters spectral correlations: it generates quasi-degenerate Floquet doublets localised at opposite momenta, whose exponentially small splittings produce a hierarchy of exponentially large dynamical timescales. The coherent backscattering and forward-scattering peaks then exhibit a striking non-monotonic evolution and strongly asymmetric contrasts, followed by an exceptionally slow logarithmic relaxation toward a common asymptotic value – a hallmark of glassy dynamics, here emerging in a fully coherent quantum system. That such archetypal glass-like behaviour arises from a single discrete symmetry constraint reveals an unexpected and deep connection between quantum coherence and slow relaxation phenomena.

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