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We investigate the thermodynamic phase transitions of a four-dimensional charged anti-de Sitter black hole endowed with a non-minimal coupling of the form . Using perturbative methods, we derive a consistent black hole solution and analyze its thermodynamics through both conventional equilibrium techniques and a topological defect classification approach. The system displays van der Waals-like critical behavior, with a swallow-tail structure in the free energy and distinct phase branches. The topological analysis independently confirms the existence of critical points and classifies the system within the universal topological scheme for black hole thermodynamics.

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