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For and consider the tree on vertices which is obtained by adding pendant vertices to one degree vertex of the path . We call the trees as path-star trees. We prove that over all trees on vertices, the distance between center and subtree core and the distance between centroid and subtree core are maximized by some path-star trees. We also prove that the tree maximizes both the distances among all path-star trees on vertices, where is the smallest positive integer such that

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