We show obstructions to the existence of a coclosed -structure on a Lie algebra of dimension seven with non-trivial center. In particular, we prove that if there exist a Lie algebra epimorphism from to a six-dimensional Lie algebra , with kernel contained in the center of , then any coclosed -structure on induces a closed and stable three form on that defines an almost complex structure on . As a consequence, we obtain a classification of the 2-step nilpotent Lie algebras which carry coclosed -structures. We also prove that each one of these Lie algebras has a coclosed -structure inducing a nilsoliton metric, but this is not true for 3-step nilpotent Lie algebras with coclosed -structures. The existence of contact metric structures is also studied.

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