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In this paper, we study the Cauchy problem for a heat equation governed by a mixed local–nonlocal diffusion operator with spatially irregular coefficients. We first establish classical well-posedness in an energy framework for bounded, measurable coefficients that satisfy uniform positivity, and we derive an a priori estimate ensuring uniqueness and continuous dependence on the initial data. We then extend the notion of solution to distributional coefficients and initial data by a Friedrichs-type regularisation procedure. Within this very weak framework, we establish the existence and uniqueness of solution nets and prove consistency with the classical weak solution whenever the coefficients are regular.

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