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We obtain predictions for and $B_{(s)}\to \mu^+\mu^-\gamma$ decays. All the contributions containing long-distance QCD effects are calculated in the framework of relativistic quark model. The contributions of the light vector-meson resonances related to the virtual photon emission from valence quarks of the -meson are included. The highest branching ratios for the radiative leptonic B-decays are ${\cal B}(\bar B^0_s\to e^+e^-\gamma)=18.8\times10^{-9}{\cal B}(B^0_s\to \mu^+\mu^-\gamma)=12.2\times10^{-9}$. We also give the distribution of the foward-backward asymmetry.

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