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We report on the experimental realization of a ten-photon Greenberger-Horne-Zeilinger state using thin BiBO crystals. The observed fidelity is , demonstrating a genuine entanglement with a standard deviation of 3.6 . This result is further verified using -value calculation, obtaining an upper bound of under an assumed hypothesis test. Our experiment paves a new way to efficiently engineer BiBO crystal-based multi-photon entanglement systems, which provides a promising platform for investigating advanced optical quantum information processing tasks such as boson sampling, quantum error correction and quantum-enhanced measurement.

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