We study the spectrum of a self-adjoint Dirac-Krein operator with potential on a compact star graph with a finite number of edges. This operator is defined by a Dirac-Krein differential expression with summable matrix potentials on each edge, by self-adjoint boundary conditions at the outer vertices, and by a self-adjoint matching condition at the common central vertex of . Special attention is paid to Robin matching conditions with parameter . Choosing the decoupled operator with Dirichlet condition at the central vertex as a reference operator, we derive Krein’s resolvent formula, introduce corresponding Weyl-Titchmarsh functions, study the multiplicities, dependence on , and interlacing properties of the eigenvalues, and prove a trace formula. Moreover, we show that, asymptotically for , the difference of the number of eigenvalues in the intervals and deviates from some integer , which we call dislocation index, at most by .

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