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In this paper, we show that the twisted Poincar'e duality between Poisson homology and cohomology can be derived from the Serre invertible bimodule. This gives another definition of a unimodular Poisson algebra in terms of its Poisson Picard group. We also achieve twisted Poincar'e duality for Hochschild (co)homology of Poisson bimodules using rigid dualizing complex. For a smooth Poisson affine variety with the trivial canonical bundle, we prove that its enveloping algebra is a Calabi-Yau algebra if the Poisson structure is unimodular.

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