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In this paper, we investigate Cauchy problem of the two-dimensional full Maxwell-Navier-Stokes system, and prove the global-in-time existence and uniqueness of solution in the borderline space which is very close to -energy space by developing the new estimate of $\sup_{j\in\mathbb Z} 2^{2j} \int_0^t \sum_{k\in^2} \big| \sqrt{\phi_{i,k}} u(\tau) \big|^2_{L^2(^2)} \tau < \infty$. This solves the open problem in the framework of borderline space purposed by Masmoudi in \cite{Masmoudi-10}.

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