In this paper, we study the multiplicity and concentration of the positive solutions to the following critical Kirchhoff type problem: \begin{equation*} -\left(\varepsilon^2 a+\varepsilon b\int_{\R^3}|\nabla u|^2 x\right)\Delta u + V(x) u = f(u)+u^5\ \ {\rm in } \ \ \R^3, \end{equation*} where is a small positive parameter, , are positive constants, is a positive potential, $f \in C^1(\R^+, \R)u^5$ is a pure critical nonlinearity. When small, we establish the relationship between the number of positive solutions and the profile of the potential . The exponential decay at infinity of the solution is also obtained. In particular, we show that each solution concentrates around a local strict minima of as $\varepsilon \rightarrow 0$.

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