We investigate the electromagnetic polarizabilities of singly heavy mesons and doubly heavy baryons within the framework of heavy hadron chiral perturbation theory up to . We estimate the low-energy constants using the non-relativistic constituent quark model. A striking prediction of our study is the giant electric polarizabilities of the mesons: and . These anomalously large values arise from the near-degenerate mass between and , which are orders of magnitude larger than those of their bottom counterparts. This kinematic coincidence induces a pronounced cusp structure in the chiral loops, reflecting the long-range dynamics of a pion cloud. For doubly heavy baryons, polarizabilities depend strongly on heavy-flavor composition: the system differs markedly from and due to mixing with scalar heavy-diquark states. Using heavy diquark-antiquark symmetry (HDAS), we unify the chiral dynamics of singly heavy mesons and doubly heavy baryons in the heavy-quark limit. The pion-loop contributions dominate the electromagnetic structure of heavy hadrons and provide essential benchmarks for future lattice QCD simulations.

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