Exchange bias-like effect in TbFeAl intermetallic induced by atomic disorder

Exchange bias-like effect observed in the intermetallic compound TbFeAl, which displays a magnetic phase transition at $T_c^h\approx$ 198~K and a second one at $T_c^l\approx$ 154~K, is reported. {\em Jump}-like features are observed in the isothermal magnetization, $M(H)$, at 2~K which disappear above 8~K. The field-cooled magnetization isotherms below 10~K show loop-shifts that are reminiscent of exchange bias, also supported by {\em training effect}. Significant coercive field, $H_c\approx$ 1.5~T at 2~K is observed in TbFeAl which, after an initial increase, shows subsequent decrease with temperature. The exchange bias field, $H_{eb}$, shows a slight increase and subsequent leveling off with temperature. It is argued that the inherent crystallographic disorder among Fe and Al and the high magnetocrystalline anisotropy related to Tb${}^{3+}$ lead to the exchange bias effect. TbFeAl is recently reported to show magnetocaloric effect and the present discovery of exchange bias makes this compound a multifunctional one. The result obtained on TbFeAl generalizes the observation of exchange bias in crystallographically disordered materials and gives impetus for the search for materials with {\em exchange bias induced by atomic disorder.}