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We present exact large N calculus of four point function in general Chern-Simons bosonic and fermionic vector models. Applying the LSZ formula to the four point function we determine two body scattering amplitudes in these theories taking a special care for a non-analytic term to achieve unitarity in the singlet channel. We show that the S-matrix enjoys the bosonization duality, unusual crossing relation and non-relativistic reduction to Aharonov-Bohm scattering. We also argue that the S-matrix develops a pole in a certain range of coupling constants, which disappears in the range where the theory reduces to Chern-Simons theory interacting with free fermions.

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