In this paper, we aim to provide probabilistic and combinatorial insights into tree formulas for the Green function and hitting probabilities of Markov chains on a finite state space. These tree formulas are closely related to loop-erased random walks by Wilson’s algorithm for random spanning trees, and to mixing times by the Markov chain tree theorem. Let be the mean first passage time from to for an irreducible chain with finite state space and transition matrix . It is well-known that , where is the stationary distribution for the chain, is the tree sum, over trees spanning with root and edges directed to , of the tree product , and . Chebotarev and Agaev derived further results from {\em Kirchhoff’s matrix tree theorem}. We deduce that for $i \ne jm_{ij} = \Sigma_{ij}/\Sigma_j\Sigma_{ij}$ is the sum over the same set of spanning trees of the same tree product as for , except that in each product the factor is omitted where $k = k(i,j,)jij\sum_{j \in S} m_{ij}/m_{jj} \Sigma^{(2)}/\Sigma^{(1)}\Sigma^{®}$ is the sum, over all forests labeled by with trees, of the product of over edges of . We show that these results can be derived without appeal to the matrix tree theorem. A list of relevant literature is also reviewed.

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