This paper is concerned with the numerical approximation of the Dirichlet eigenpairs of the operator on a simply connected bounded domain containing the origin, where is a radial potential. We propose a mesh-free method inspired by the Method of Particular Solutions for the Laplacian (i.e. ). Extending this approach to general radial potentials is challenging due to the lack of explicit basis functions analogous to Bessel functions. To overcome this difficulty, we consider the equation on a ball containing , without imposing boundary conditions, for a collection of values forming a fine discretisation of the interval in which eigenvalues are sought. By rewriting the problem in polar coordinates and applying a Fourier expansion with respect to the angular variable, we obtain a decoupled system of ordinary differential equations. These equations are solved numerically using a one-dimensional Finite Element Method, yielding a family of basis functions that are solutions of the equation on the ball and are independent of the domain . Dirichlet eigenvalues of are then approximated by minimising the boundary values on among linear combinations of the basis functions and identifying those values of for which the computed minimum is sufficiently small. The proposed method is highly memory-efficient compared to the standard Finite Element approach.

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