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We report first results from RadioAxion, an underground experiment searching for axion dark matter through periodic modulations of radioisotope decays. We monitor the decay of Am via its keV line using a NaI detector installed at the Gran Sasso Laboratory, where cosmic-ray-induced systematics are strongly suppressed. We present the measured spectra and the corresponding time-series analysis. No evidence for a periodic modulation is observed. From these data we derive constraints on the axion decay constant in the axion mass range from to eV.

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