We analyze reactive collisions of a single Ba ion in contact with an ultracold gas of Rb atoms at low three-body collision energies of 2.2(9) mK. Mapping out the Ba loss rate dependence on the Rb atom density we can discern two-body reactive collisions from three-body ones and for the first time determine both rate coefficients which are and , respectively (statistical and systematic errors in parenthesis). Thus, the measured ternary recombination dominates over binary reactions even at moderate atom densities of . The results for Ba and Rb are representative for a wide range of cold ion-atom systems and can serve as a guidance for the future development of the field of hybrid atom-ion research.

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