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For a finite group , the proper power graph of is the graph whose vertices are non-trivial elements of and two vertices and are adjacent if and only if and or for some positive integer . In this paper, we consider the complement of , denoted by . We classify all finite groups whose complement of proper power graphs is complete, bipartite, a path, a cycle, a star, claw-free, triangle-free, disconnected, planar, outer-planar, toroidal, or projective. Among the other results, we also determine the diameter and girth of the complement of proper power graphs of finite groups.

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