Single-layer MoS${}_2$ on Au(111): band gap renormalization and substrate interaction

The electronic structure of epitaxial single-layer MoS${}_2$ on Au(111) is investigated by angle-resolved photoemission spectroscopy, scanning tunnelling spectroscopy, and first principles calculations. While the band dispersion of the supported single-layer is close to a free-standing layer in the vicinity of the valence band maximum at $\bar{K}$ and the calculated electronic band gap on Au(111) is similar to that calculated for the free-standing layer, significant modifications to the band structure are observed at other points of the two-dimensional Brillouin zone: At $\bar{\mathrm{\Gamma }}$, the valence band maximum has a significantly higher binding energy than in the free MoS${}_2$ layer and the expected spin-degeneracy of the uppermost valence band at the $\bar{M}$ point cannot be observed. These band structure changes are reproduced by the calculations and can be explained by the detailed interaction of the out-of-plane MoS${}_2$ orbitals with the substrate.