In the present work we discuss inter-species entanglement in Bose-Bose mixtures trapped in optical lattices. This work is motivated by the observation that, in the presence of a second component, the Mott-insulator lobe shifts {\em{differently}} on the hole- and particle-side with respect to the Mott lobe of the single species system (Phys. Rev. A 82, 021601, Laser Phys. 21, 1443). We use perturbation theory, formulated in a Hilbert space decomposed by means of lattice symmetries, in order to show that the nonuniform shift of the Mott lobe is a consequence of an inter-species entanglement which differs in the lowest excited states to remove and add a particle. Our results indicate that inter-species entanglement in mixtures can provide a new perspective in understanding quantum phase transitions. To validate our approach, we compare our results from perturbation theory with quantum Monte Carlo simulations.

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