This is a continuation to the paper [arXiv:1511.08164] in which a problem of minimizing normalized volumes over -Gorenstein klt singularities was proposed. Here we consider its relation with K-semistability, which is an important concept in the study of K"{a}hler-Einstein metrics on Fano varieties. In particular, we prove that for a -Fano variety , the K-semistability of is equivalent to the condition that the normalized volume is minimized at the canonical valuation among all -invariant valuations on the cone associated to any positive Cartier multiple of . In this case, it’s shown that is the unique minimizer among all -invariant quasi-monomial valuations. These results allow us to give characterizations of K-semistability by using equivariant volume minimization, and also by using inequalities involving divisorial valuations over .

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