We study the probability that two directed polymers in a given random potential and with fixed and nearby endpoints, do not cross until time . This probability is itself a random variable (over samples ) which, as we show, acquires a very broad probability distribution at large time. In particular the moments of are found to be dominated by atypical samples where is of order unity. Building on a formula established by us in a previous work using nested Bethe Ansatz and Macdonald process methods, we obtain analytically the leading large time behavior of {\it all moments} . From this, we extract the exact tail of the probability distribution of the non-crossing probability at large time. The exact formula is compared to numerical simulations, with excellent agreement.

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