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We present a compact, cost-effective method for measuring the emittance of kHz-repetition-rate laser-wakefield accelerated electron beams using a permanent solenoid. The measured normalized emittance, () at MeV, is comparable to that of ultra-low emittance radiofrequency guns used for electron diffraction. Leveraging this low emittance, we successfully applied the electron beam to electron diffraction. We demonstrate diffraction images obtained from a single crystal Silicon nano-membrane sample, clearly resolving diffraction peaks across multiple orders.

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