Competing Ordering Modes in the Distorted Quantum Kagome Material Clinoatacamite Cu${}_2$Cl(OH)${}_3$

We have studied the magnetic properties of clinoatacamite Cu${}_2$Cl(OH)${}_3$, the parent compound of the quantum spin liquid candidate herbertsmithite and a longstanding puzzle among frustrated quantum magnets. As we reveal using density-functional theory, clinoatacamite belongs to the class of distorted kagome antiferromagnets with the kagome plane being embedded into a low-symmetry crystal structure. By means of thermodynamic measurements, muon spin rotation/relaxation as well as neutron diffraction on single crystals, we find a complex sequence of phases/regions below 18.1 K in zero magnetic field. We propose this complexity in multicritical clinoatacamite to arise from the competition of antiferromagnetic ordering modes from the underconstrained manifold of modes, which can lead to a metamagnetic texture in zero magnetic field.