We study the bispectrum, generated by correlations between Cosmic Microwave Background temperature (T) anisotropies and chemical potential () distortions, and we analyze its dependence on primordial local trispectrum parameters and . We cross-check our results by comparing the full bispectrum calculation with the expectations from a general physical argument, based on predicting the shape of -T correlations from the couplings between short and long perturbation modes induced by primordial non-Gaussianity. We show that and -parts of the primordial trispectrum source a non-vanishing signal, contrary to the auto-correlation function, which is sensitive only to the -component. A simple Fisher matrix-based forecast shows that a futuristic, cosmic-variance dominated experiment could in principle detect and using .

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