We study the magnetic structures and their connections with topological superconductivity due to proximity effect for coupled magnetic atomic chains deposited on a superconductor. Several magnetic phases are self-consistently determined, including both the coplanar and non-coplanar ones. For a -chain triangular atomic ladder, topologically nontrivial superconducting states can always be realized, but strongly depend on its magnetic structure and the number of atomic chains. When is even, the topologically nontrivial states with noncoplanar structures are characterized by invariants, while the topologically nontrivial noncoplanar states with an odd are characterized by integer invariants, due to the presence of a new chiral symmetry. The new chiral symmetry for the noncoplanar states is found to be robust against the on-site disorder, as long as the crystal reflection symmetry is respected.

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