In this paper, we studied the and $\rho\gamma^\to \rho\rho\piQ^4 F_{\rho\pi}(Q^2)\rho$ meson electromagnetic form factors, and , by employing the perturbative QCD (PQCD) factorization approach. For the $\rho \gamma^ \to \piQ^4 F_{\rho\pi}(Q)$ from the term proportional to the distribution amplitude combination is absolutely dominant, and the PQCD predictions for both the size and the -dependence of this form factor agree well with those from the extended ADS/QCD models or the light-cone QCD sum rule. For the transition and in the region of GeV, further more, we found that the PQCD predictions for the magnitude and their -dependence of the and form factors agree well with those from the QCD sum rule, while the PQCD prediction for is much larger than the one from the QCD sum rule.

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