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In this paper, operator-valued bi-free distributions are investigated. Given a subalgebra of a unital algebra , it is established that a two-faced family is bi-free from over if and only if certain conditions relating the -valued and -valued bi-free cumulants of are satisfied. Using this, we verify that a two-faced family of matrices is -cyclic if and only if they are bi-free from the scalar matrices over the scalar diagonal matrices. Furthermore, the operator-valued bi-free partial -, -, and -transforms are constructed. New proofs of results from free probability are developed in order to facilitate many of these bi-free results.

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