Suppose is a Schr"odinger operator on with a potential belonging to certain reverse H"older class with . The main aim of this paper is to provide necessary and sufficient conditions in terms of criteria for a generalised Calder'on–Zygmund type operator with respect to to be bounded on Hardy spaces and on BMO type spaces BMO associated with . As applications, we prove the boundedness for several singular integral operators associated to . Our approach is flexible enough to prove the boundedness of the Riesz transforms related to with which were investigated in \cite{MSTZ} under the stronger condition . Thus our results not only recover existing results in \cite{MSTZ} but also contains new results in literature.

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