Let be a bijection (not assumed affine nor continuous) between the sets of normal states of two quantum systems, modelled on the self-adjoint parts of von Neumann algebras and , respectively. This paper concerns with the situation when preserves (or partially preserves) one of the following three notions of “transition probability” on the normal state spaces: the Uhlmann transition probability , the Raggio transition probability and an “asymmetric transition probability” as defined in this article. It is shown that the two systems are isomorphic, i.e. and are Jordan -isomorphic, if preserves all pairs with zero Uhlmann (respectively, Raggio or asymmetric) transition probability, i.e., for any normal states and , we have where stands for (respectively, or ). Furthermore, as an extension of Wigner’s theorem, it is shown that there is a Jordan -isomorphism $\Theta:M_2\to M_1\Phi\Phi\Phi$ preserves the Raggio transition probability, it will preserve the Uhlmann transition probability as well. As another application, the sets of normal states equipped with either the usual metric, the Bures metric or “the metric induced by the self-dual cone” are complete Jordan -invariants for the underlying von Neumann algebras.

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