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Let be a quiver with dimension vector prehomogeneous under the action of the product of general linear groups on the representation variety . We study geometric properties of zero sets of semi-invariants of this space. It is known that for large numbers , the nullcone in becomes a complete intersection. First, we show that it also becomes reduced. Then, using Bernstein-Sato polynomials, we discuss some criteria for zero sets to have rational singularities. In particular, we show that for Dynkin quivers codimension orbit closures have rational singularities.

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