In this work, we study the semileptonic decay modes $B_s^0\to \pi^+\pi^-\ell^+\ell^-D_s^+\to \pi^+\pi^-\ell^+ \nu$ in the kinematics region where the system has a invariant mass in the range - GeV. These processes are valuable towards the determination of S-wave light-cone distribution amplitudes whose normalizations are scalar form factors. We compare the results for scalar form factors predicted in unitarized chiral perturbation theory and extracted from the data on the . Then the and $D_s\to \pi^+\pi^-$ form factors are calculated in light-cone sum rules, based on which predictions for differential decay widths are made. The results are in good agreement with the experimental data on the and decays into . More accurate measurements at BEPC, LHC and KEKB in future will be helpful to examine our formalism and constrain the input parameters more precisely.

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